Chiral base-mediated rearrangement of meso-cyclohexene oxides to allylic alcohols
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Keywords:
Lithium amide
Cyclohexenone
Diastereomer
Allylic alcohol
Cyclohexene oxide
Amide
Base (topology)
Cyclohexene oxide
Polystyrene
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Diastereomer
Lithium amide
Cyclohexene oxide
Cyclohexanes
Amide
Allylic alcohol
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Lithium amide
Cyclohexenone
Diastereomer
Allylic alcohol
Cyclohexene oxide
Amide
Base (topology)
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Cyclohexene oxide
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Benzil
Cyclohexene oxide
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Cyclohexene oxide
Homolysis
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Abstract The epoxidation of cyclohexene using CrO3/tert.‐butylhydroperoxide gives cyclohexene oxide, cyclohexenol and cyclohexenone in the ratio 3:1:40.
Cyclohexene oxide
Cyclohexenone
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Cyclohexene oxide
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Abstract Epoxidation reaction catalyzed by dicyclohexylcarbodiimide(DCC) was realized in a microflow system, resulting in cyclohexene oxide with high yields. In this study, the epoxidation process of cyclohexene in MFS was investigated in detail. The optimal yield was obtained in such conditions: temperature 80°C, residence time 12 min, catalyst concentration 3%, ratio of cyclohexene to UHP 1:8. Basic additions played an important role in the collapse of adducts.
Cyclohexene oxide
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