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    Polyfluorination of Aryl Alkyl Sulfides by IF5 with Concomitant Migration of the Arylthio Group
    Organic Letters (2003)
    Shinichi AyubaTsuyoshi FukuharaShoji Hara
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    Abstract:
    [reaction: see text] In the reaction of p-chlorophenyl alkyl sulfides with IF(5), polyfluorination reaction took place on the alkyl chain with the migration of the arylthio group. Consequently, p-chlorophenyl polyfluoroalkyl sulfides, having 3-7 fluorine atoms depending on alkyl chain length, could be obtained selectively.
    Keywords:
    Concomitant
    Chain (unit)
    Fluorine
    Topics:
    Fluorine in Organic Chemistry
    Inorganic Fluorides and Related Compounds
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