Anisotropic Thermopower of the Kondo Insulator CeRu4Sn6 (vol 43, pg 2440, 2014)
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We studied the macroscopic properties of Ce x La 1- x Ru 2 Al 10 single crystal. From the results of the rapid suppression of the anomaly at T 0 and thermally activated-type behavior and the increase of the γ T term by La doping, we propose that the low-energy magnetic excitation may be induced, which may be related to the randomly suppressed high energy magnetic excitation. We also studied Ce 0.1 Y 0.9 Fe 2 Al 10 single crystal, and found that Ce ion in this compound is nonmagnetic although in Ce 0.1 La 0.9 Ru 2 Al 10 Ce ion is magnetic and a typical impurity Kondo effect is observed.
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The intermetallic compound $$\hbox {CeRu}_4\hbox {Sn}_6$$ has been tentatively classified as Kondo insulator. This class of material, especially non-cubic representatives, is not yet fully understood. Here we report thermopower measurements on single-crystalline $$\hbox {CeRu}_4\hbox {Sn}_6$$ between 2 K and 650 K, along the main crystallographic directions. Large positive thermopower is observed in the directions along which the hybridization is strong and a Kondo insulating gap forms. A negative contribution to the thermopower dominates for the crystallographic $$c$$ axis where hybridization is weak and metallicity prevails.
Kondo insulator
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