Crystal Structure of a New Ordered form of Ammonium Hydrogen Succinate NH4HC4H4O4
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Triclinic crystal system
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The title compound CuN2O2C16H16 [Cu(PP)2] crystallizes in the triclinic system, space group P[unk], with a = 10.667(4) Å, b = 10.553(4) Å, c = 9.964(4) Å, α = 105.2°, β = 97.8°, γ = 87.9° {σ = 0.2°), Z = 3. The structure which consists of trimers of CuN2O2C16H16 exhibits hexa- and penta-coordinated copper atoms. The crystal structure has been refined to R = 0.038 for 2268 observed reflections.
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C12H15N7O2, M = 546.59, triclinic space group P[unk], a = 7.578(2), b = 9.082(3), c = 11.966(1) Å, α = 99.49(2), β = 90.84(2), γ = 114.34(3)°, Z = 2, V = 737(1) Å3, Dx = 1.303 g/cm−3, λ = 0.71069 Å, μ = 0.9 cm−1, F(000) = 304. The crystal structure was determined by direct methods and refined by least-squares procedure to a discrepancy factor R = 0.040 (Rw = 0.037).
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