A MoS2/sulfur-doped carbon sphere nanohybrid catalyst with high-efficiency electrocatalysis for flexible counter electrodes
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Molybdenum disulfide
Auxiliary electrode
Carbon fibers
Triiodide
Abstract Die Komplexe (I)‐(III) wurden durch Abziehen von Sauerstoff durch Ethyldiphenylphosphin aus Dioxo‐Mo(VI)‐Komplexen der Schiffschen Basen bzw. des Diamindithiols "in MeCN in Gegenwart der Heterocyclen bzw. des DMF dargestellt.
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Coprecipitation
Selective catalytic reduction
Brønsted–Lowry acid–base theory
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Triiodide
Auxiliary electrode
Nickel sulfide
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Graphene film was fabricated using graphene oxide (GO) prepared from a modified Hummers' method. The reduction of GO (rGO) was accomplished by coating the GO paste on a piece of glass and immersing into a Ti +3 solution. The freeze drying (FD) process employed for drying GO before its forming of paste and coating into a film exhibits a profound effect on the quality of final graphene counter electrode. The graphene electrode obtained using freeze drying process exhibits a porous structure and is an excellent replacement for the Pt counter electrode of dye-sensitized solar cells (DSSCs). The conversion efficiency for the FD-rGO-based DSSC reaches 6.21%, which is much higher than that of the normal Pt-based DSSC 5.62% using standard P25 materials. The much more reaction sites on the porous FD-rGO-film electrode than the smooth Pt electrode are considered to be the major reason for this high performance.
Auxiliary electrode
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Hydrodenitrogenation
Hydrogen sulphide
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Carbon contained in the lubricating grade molybdenum disulfide prepared with natural method,not only reduces product purity,but also affects the usability.Based on the analysis of carbon source,the method of pretreating molybdenum concentrates which is the raw materials of molybdenum disulfide at high temperature was put forward.The effect of nitrogen flow rate,temperature and time in the carbon content of molybdenum concentrates was inspected.The lubricating grade molybdenum disulfide was prepared by molybdenum concentrates treated in high temperature with nitrogen,which can reduce 30% carbon content.The purity of molybdenum disulfide can increase by 0.3%.
Molybdenum disulfide
Carbon fibers
Carbon disulfide
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Carbon and sulfur in molybdenum powder and molybdenum products were determined using CS-600 carbon/sulfur determinator.The proper operation method,the appropriate amount of specimen and latent solvent were selected,and the satisfactory results were attained.
Carbon fibers
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Molybdenum disulfide
Dry lubricant
Reciprocating motion
Base (topology)
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Electrochemical energy conversion
Electrochemical cell
Carbon fibers
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Triiodide
Auxiliary electrode
Molybdenum disulfide
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