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    Flexible Polymer Device Based on Parylene-C with Memory and Temperature Sensing Functionalities
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    Abstract:
    Polychloro-para-xylylene (parylene-C) is a flexible and transparent polymer material which has excellent chemical stability and high biocompatibility. Here we demonstrate a polymer device based on single-component parylene-C with memory and temperature sensing functionalities. The device shows stable bipolar resistive switching behavior, remarkable storage window (>10⁴), and low operation voltages, exhibiting great potential for flexible resistive random-access memory (RRAM) applications. The I-V curves and conductive atomic force microscopy (CAFM) results verify the metallic filamentary-type switching mechanism based on the formation and dissolution of a metal bridge related to the redox reaction of the active metal electrode. In addition, due to the metallic properties of the low-resistance state (LRS) in the polymer device, the resistance in the LRS exhibits a nearly linear relationship at the temperature regime between 25 °C and 100 °C. With a temperature coefficient of resistance (TCR) of 2.136 × 10-3/°C, the device is also promising for the flexible temperature sensor applications.
    Keywords:
    Parylene
    Shape-memory polymer
    Porous SiC ceramics with multiple pore structures were fabricated via gelcasting and solid state sintering.A novel gelling agent of Isobam was applied and PMMA was used as both foam stabilizer and pore forming agent.The mechanical properties of porous SiC ceramics were investigated as functions of PMMA content, rotating speed of ball mill, and sintering temperature.With PMMA content increasing from 5wt% to 20wt%, the foaming effect was inhibited while the stability of bubbles increased.When the rotating speed was 220 r/min, the open porosities of the as-prepared SiC ceramics sintered at 2100 varied ℃ from 51.5% to 72.8%, and compressive strength varied from 7.9 to 48.2 MPa.With the rotating speed increasing from 220 to 280 r/min, the foaming effect was aggravated and the porosities of SiC ceramics sintered at 2100 increased.℃ While the sintering temperature increasing from 2050 to 2150 , ℃ the SiC ceramics prepared with PMMA content of 20wt% at rotating speed of 220 r/min decreased in the open porosities while increased in compressive strength.
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    ZrB2 based composites containing 10 vol.-% carbon nanotubes (CNTs) are synthesised by spark plasma sintering at temperatures ranging from 1600 to 18008C and at an applied pressure of 25 MPa. The effects of sintering temperature on densification behaviour, microstructural evolutions and mechanical properties are presented. Results indicate that ZrB2-CNT composites fabricated at 16508C have the optimal combination of dense microstructure and properties. The fracture toughness is sensitive to the temperature change and reaches 7.2 MPa m1/2 for the CNT toughened ZrB2 ceramics, which is higher than the measured result for monolithic ZrB2 (3.3 MPa m1/2). The crack deflection and CNT pullout are the dominant toughening mechanisms.
    Spark Plasma Sintering
    Toughening
    Parylene films deposited on liquid surface induce film tension that changes the liquid shape. We observed that the force acting on the surface of Parylene-C encapsulated liquid bodies increased continuously during Parylene deposition process and reached final values of magnitude more than 700 ¿N/mm for a 1 ¿m thick film, 20 times larger than the surface tension of the encapsulated liquid. This surface force can only be attributed to the tension of the Parylene films. This founding requires that in design of Parylene encapsulated liquid structures, Parylene film tension must be considered as the main factor that determines the structures' final shape.
    Parylene
    Tension (geology)
    Deposition
    Cell patterning is becoming increasingly popular in neuroscience because it allows for the control in the location and connectivity of cells. A recently developed cell patterning technology uses patterns of an organic polymer, parylene-C, on a background of SiO2. When cells are cultured on the parylene-C/SiO2 substrate they conform to the underlying parylene-C geometry. Parylene-C is, however, just one member of a family of parylene polymers that have varying chemical and physical properties. In this work, we investigate whether two commercially available mainstream parylene derivatives, parylene-D, parylene-N and a more recent parylene derivative, parylene-HT to determine if they enable higher fidelity hNT astrocyte cell patterning compared to parylene-C. We demonstrate that all parylene derivatives are compatible with the existing laser fabrication method. We then demonstrate that parylene-HT, parylene-D and parylene-N are suitable for use as an hNT astrocyte cell attractive substrate and result in an equal quality of patterning compared to parylene-C. This work supports the use of alternative parylene derivatives for applications where their different physical and chemical properties are more suitable.
    Parylene