Synergistic effect between Pt0 and Bi2O3−x for efficient room-temperature alcohol oxidation under base-free aqueous conditions
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Abstract:
The synergistic effect between Pt0 and nearby partially reduced Bi2O3−x species was found to be efficient (conversion of 94.1 ± 2.7%, selectivity to aldehyde >99%) for benzyl alcohol oxidation at room temperature (26 °C) under base-free aqueous conditions.Keywords:
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C. L. Arcus and H. E. Strauss, J. Chem. Soc., 1952, 2669 DOI: 10.1039/JR9520002669
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Dry and wet prolines were found to catalyze the direct aldol reactions of aldehyde-aldehyde and aldehyde-ketone, respectively, to afford aldols with excellent diastereo- and enantioselectivities, and an organic solvent-free reaction was realized in some cases.
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Abstract Phenylpropargyl aldehyde intermediate: α‐Bromocinnamic aldehyde intermediate: α‐ Bromocinnamic aldehyde acetal intermediate: phenylpropargyl aldehyde acetal product: phenylpropargyl aldehyde
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the reductivity of aldehyde and ketone was compared,the reaction of aldehyde and weak oxidizer was discussed,and it was pointed out that Fehling Reagent can't appreciate aldihyde and ketone,fatty aldehyde and aromatic aldehyde.
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The oxidation of alcohols by argentic picolinate has been studied and has been shown to give high yields of aldehyde and ketone. Examination of the oxidation of aldehydes shows that smooth conversion to the acid occurs in most cases, but in some cases, an anomalous reaction occurs, which probably involves attack upon the aromatic ring of substituted benzaldehydes. The oxidation of aldehydes occurs much more slowly than alcohol-oxidation under similar conditions.
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