Detection of latent fingerprints based on gas phase adsorption of NO and subsequent application of an ultrasonically nebulized fluorescent probe
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A method for detecting latent fingerprints based on the adsorption of NO gas and an ultrasonically nebulized NO probe was developed.The application of ion cyclotron resonance spectroscopy to the stUdy of organometallic reactions is described.Methodology is outlined for the determination of metal-hydrogen, metal-carbon and metal-ligand bond dissociation energies and representative results are given.These data are of fundamental importance in understanding the reactions of organic molecules at transition metal centers.Decarbonylation of aldehydes and dehydrogenation of alkanes are treated as examples of oxidative addition processes.Elimination of methane from hydrido methyl complexes exemplifies the study of reductive elimination reactions.Additional examples include studies of the acylation and alkylation of metal complexes, and the reactions of molecular hydrogen with several coordinatively unsaturated species.
Decarbonylation
Oxidative addition
Reductive elimination
Metal carbonyl
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Abstract The acidities of radical cations derived from PhSH, PhOH, cyclopentadiene, PhCH 2 CN, fluorene, PhNH 2 , Ph 2 CH 2 , and toluene are estimated in DMSO and in the gas phase by combination of acidity data for the parent acids (pKHA) with oxidation potentials for HA (Eox(HA) in DMSO and IP(HA) in the gas phase) and with oxidation potentials for A‐ (Eox(A‐) in DMSO and EA(A·) in the gas phase).
Cyclopentadiene
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTExperimental determination of the acidity and basicity of glycine in the gas phaseMichael J. Locke, Richard L. Hunter, and Robert T. McIver Jr.Cite this: J. Am. Chem. Soc. 1979, 101, 1, 272–273Publication Date (Print):January 1, 1979Publication History Published online1 May 2002Published inissue 1 January 1979https://pubs.acs.org/doi/10.1021/ja00495a073https://doi.org/10.1021/ja00495a073research-articleACS PublicationsRequest reuse permissionsArticle Views200Altmetric-Citations58LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStructural effects on the iodine cation basicity of organic bases in the gas phaseJose Luis M. Abboud, Rafael Notario, Lucia Santos, and Carmen Lopez-MardomingoCite this: J. Am. Chem. Soc. 1989, 111, 24, 8960–8961Publication Date (Print):November 1, 1989Publication History Published online1 May 2002Published inissue 1 November 1989https://pubs.acs.org/doi/10.1021/ja00206a052https://doi.org/10.1021/ja00206a052research-articleACS PublicationsRequest reuse permissionsArticle Views142Altmetric-Citations10LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts
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Sodium chloride dihydrates form cuboid structures in initial stages of nucleation, preserving the NaCl interaction.
Cuboid
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Langmuir adsorption model
Carbon fibers
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