PHYSICAL CHEMISTRY OF NANOCLUSTERS AND NANOMATERIALS NMR Investigation of the Porosity of Hypercrosslinked Polystyrene and the Properties of Water Confined in Its Nanopores
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A facile way to synthesize nanometer-sized polymer (polypyrrole, PPy) particles is explored on the basis of the formation of complexes between water-soluble polymers and metal cations in aqueous solution. The metal cation is used as an oxidizing agent to initiate the chemical oxidation polymerization of the corresponding monomer, and the water-soluble polymer effectively provides a steric stability for the growth of polymer nanoparticles during the polymerization process. Light-scattering analyses are performed to give insight into the behavior of the complexes in aqueous solution. In addition, major physical parameters affecting the formation of polymer nanoparticles are investigated, including hydrodynamic radius, radius of gyration, shape factor, and viscosity. By judicious control of these parameters, PPy nanoparticles with narrow size distribution can be readily fabricated in large quantities. It is also possible to control the diameter of the nanoparticles by changing critical synthetic variables. Importantly, PPy nanoparticles of approximately 20-60 nm in diameter can be prepared without using any surfactants or specific templates; this novel strategy offers great possibility for mass production of polymer nanoparticles.
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Nanoconfined synthesized crystalline fullerene mesoporous carbon (C60-FMC) with bimodal pore architectures of 4.95 nm and 10-15 nm pore sizes characterized by XRD, TEM, nitrogen adsorption/ desorption isotherm and solid-state NMR, and the material was used for protein immobilization. The solid-state 13C NMR spectrum of C60-FMC along with XRD, BET and TEM confirms the formation of fullerene mesoporous carbon structure C60-FMC. The immobilization of albumin (from bovine serum, BSA) protein biomolecule in a buffer solution at pH 4.7 was used to determine the adsorption properties of the C60-FMC material and its structural changes investigated by FT-IR. We demonstrated that the C60-FMC with high surface area and pore volumes have excellent adsorption capacity towards BSA protein molecule. Protein adsorption experiments clearly showed that the C60-FMC with bimodal pore architectures (4.95 nm and 10-15 nm) are suitable material to be used for protein adsorption.
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Abstract Helium ion microscopy (HIM) is a relatively new high-resolution nanotechnology imaging and nanofabrication tool. HIM offers a near-molecular resolution (approaching that of TEM) combined with a simplicity of sample preparation and high depth of field similar to SEM. Simultaneously, the technique is not limited by the surface roughness as scanning probe microscopy (SPM) techniques or by the surface charging or radiation damage like SEM. In our review, we consider general principles, advantages, and prospects of HIM application in polymer science. Examples of high-resolution imaging of polymer-based nanocomposites, polymer nanoparticles, nanofibers, nanoporous materials, polymer nanocrystals, biopolymers, and polymer-based photovoltaic and sensor devices are presented. We compare the HIM’s applicability with other modern imaging techniques: SPM and SEM.
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