Synthesis and Characterization of Fluorodinitroamine, FN(NO2)2
Karl O. ChristeWilliam W. WilsonGuillaume Bélanger‐ChabotRalf HaigesJerry A. BoatzMartin RahmG. K. Surya PrakashThomas SaalMathias Hopfinger
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Abstract NF 3 and N(NO 2 ) 3 are known compounds, whereas the mixed fluoronitroamines, FN(NO 2 ) 2 and F 2 NNO 2 , have been unknown thus far. One of these, FN(NO 2 ) 2 , has now been prepared and characterized by multinuclear NMR and Raman spectroscopy. FN(NO 2 ) 2 is the first known example of an inorganic fluoronitroamine. It is a thermally unstable, highly energetic material formed by the fluorination of the dinitramide anion using NF 4 + salts as the preferred fluorinating agent.Keywords:
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