Structure of intercalated compounds of graphite fluoride C2FX
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Fluorine
Solid-state physics
This chapter contains sections titled: Preparation of Graphite Fluorides, (CF) n and (C 2 F) n Preparation of Fluorine-Graphite Intercalation Compound, C x F Preparation of Fluoride- and Oxide Fluoride-Graphite Intercalation Compounds References
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Synthesis, structures, and physicochemical properties of fluorine-graphite intercalation compounds synthesis and structures of main group fluoride-and transition metal fluoride-graphite intercalation compounds some thermodynamic aspects of the intercalation of graphite by fluoroanions physical properties of fluorine and fluoride graphite intercalation compounds synthesis, structures, and intercalation chemistry of B/C/N materials based on the graphite network fluorinated fullerenes electrochemical properties of graphite fluorides and metal fluorides and oxide fluorides GICs carbon anode reaction in fluorine production metal fluoride-impregnated new carbon anode for fluorine production tribology of graphite fluorides new composition with superhydrophobicity.
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Abstract Ternäre Einschlußverbindungen wie (I) und (II), die chemisch an den Kohlenstoffschichten des Wirtsgraphits adsorbierte aktive F‐Atome enthalten, werden als Kathodenmaterial in Li‐Zellen eingesetzt.
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A blue-black first-stage graphite fluoride, CxF (5 > x > 2), in which the planar carbon-atom sheets of graphite are preserved, is made by intercalation of graphite with fluorine in the presence of liquid hydrogen fluoride, at ca. 20 °C, the oxidation (which is electrochemically reversible for x > 2.6) proceeding via a highly conductive second stage salt: C12+HF2–.
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Graphite intercalation compound
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Vanadium fluoride-graphite intercalation compounds have been prepared under a relatively high vapor pressure of VF5 in a fluorine atmosphere. GISs having larger inter-calate sizes than those for VF5 and VF-6 are abtained under this condition. ESCA and IR spectra indicate that the intercalates of these compounds are VF5 and fluorine. Based on these results, new c-axis structure models have been proposed.
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