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    Transport and magnetic study of the spin reorientation transition in the Tb5(Si0.5Ge0.5)4magnetocaloric compound
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    Abstract:
    Detailed measurements of the electrical resistivity ?(T), thermopower S(T) and magnetization of Tb5(Si0.5Ge0.5)4 in the vicinity of the spin reorientation transitions observed in this compound are reported. Our results indicate a complex spin reorientation process associated with three different lattice sites occupied by the Tb ions. We identify two critical transition temperatures: one at TSR1 = 57?K, as previously reported, and a new one at TSR2 = 40?K. A simple model based on an approximate magnetic anisotropy energy is presented; it gives a satisfactory qualitative description of the main features of the reorientation processes.
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    Magnetic refrigeration
    This study investigated the improvement in magnetocaloric properties with magnetocrystalline anisotropy by Ge doping in MnFeHfPSi alloys. The maximum magnetic entropy change gets larger in alloys with higher magnetocrystalline anisotropy. This result is induced by the fractions of easy and hard magnetization planes. In addition, the magnetocaloric properties indicate large differences based on the direction between the easy magnetization plane and the applied magnetic field. Especially, the difference in magnetic entropy change under a low magnetic field is higher than that under a strong magnetic field. Besides, when magnetic transition occurs from a ferromagnetic to a paramagnetic state, the fraction of the easy magnetization plane decreases. Therefore, orientations with an easy magnetization plane play an important role in the enhancement of magnetocaloric properties.
    Magnetic refrigeration
    Magnetocrystalline anisotropy
    Magnetic shape-memory alloy
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    Co3Sn2S2 has generated a growing interest as a rare example of the highly uniaxial anisotropic kagomé ferromagnet showing a combination of frustrated-lattice magnetism and topology. Recently, via precise measurements of the magnetization and AC susceptibility we have found a low-field anomalous magnetic phase (A-phase) with very slow spin dynamics that appears just below the Curie temperature (T C). The A-phase hosts high-density domain bubbles after cooling through T C as revealed in a previous in-situ Lorentz-TEM study. Here, we present further signatures of the anomalous magnetic transition (MT) at T C revealed by a study of the critical behaviors of the magnetization and magnetocaloric effect using a high-quality single crystal. Analyses of numerous magnetization isotherms around T C (≃177 K) using different approaches (the modified Arrot plot, Kouvel-Fisher method and magnetocaloric effect) result in consistent critical exponents that do not satisfy the theoretical predictions of standard second-order-MT models. Scaling analyses for the magnetization, magnetic entropy change and field-exponent of the magnetic entropy change, all consistently show low-field deviations below T C from the universal curves. Our results reveal that the MT of Co3Sn2S2 can not be explained as a conventional second-order type and suggest an anomalous magnetic state below T C.
    Magnetic refrigeration
    Magnetism
    Citations (14)
    The zero temperature non-plateau magnetization is a peculiar property of quantum spin chain and sometimes appear due to different giro-magnetic factor. Here we illustrate the non-plateau magnetization property driven by XY-anisotropy in Ising-XYZ diamond chain. Two particles with spin-1/2 are bonded through the XYZ coupling, which is responsible for the emergence of non-plateau magnetization. These two quantum operator spins are bonded to two nodal Ising spins, and this process is repeated infinitely resulting in a diamond chain structure. This model exhibits a quite unusual non-plateau magnetization at zero temperature, we also discuss the phase diagram at zero temperature. Furthermore, owing to the non-plateau magnetization property, we focus our discussion on magnetocaloric effect of this model, illustrating isentropic curves as well as the Gr\uneisen parameters, showing the regions where the model exhibits an efficient magnetocaloric effect. Due to the existence of two phases very close to each other the strong XY-anisotropy, we obtain a peculiar behavior of magnetocaloric effect, observing a wider interval in the magnetic field, where the magnetocaloric effect is efficient.
    Magnetic refrigeration
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