In situ identification of halide complexes on gold electrode by surface-enhanced Raman spectroscopy
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTIn situ identification of halide complexes on gold electrode by surface-enhanced Raman spectroscopyB. H. LooCite this: J. Phys. Chem. 1982, 86, 4, 433–437Publication Date (Print):February 1, 1982Publication History Published online1 May 2002Published inissue 1 February 1982https://doi.org/10.1021/j100393a002RIGHTS & PERMISSIONSArticle Views393Altmetric-Citations63LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (525 KB) Get e-AlertsKeywords:
Identification
This chapter contains sections titled: Introduction Preparation of Thiocarbonyl Halides Physical Properties of Thiocarbonyl Halides Chemical Properties of Thiocarbonyl Halides Thioaroyl Chloride S-oxides References
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The effective partial pressure of low volatile halides can be increased due to the formation of gaseous complexes. It has been found that this effect can be successfully applied in high pressure gas discharge lamps leading to an enhancement of the luminous efficacy and/or an improvement of the colour rendering properties. Some selection rules have been derived for combining suitable metal halides. Lamp experiments are reported for lamps with sodium halides and the halides of the alkaline earth group, the best results being obtained with aluminium halides as the complex forming partner.
Metal halides
Sodium-vapor lamp
Gas-discharge lamp
Color rendering index
Luminous efficacy
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Abstract We have prepared a series of the title compounds 4 and 5 from the corresponding formohydroxamates and found that they are remarkably inert, resembling vinyl halides rather than the sensitive N ‐alkylimidoyl halides.
Inert
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This chapter contains sections titled: Section 136 Halides and Sulfonates from Acetylenes Section 137 Halides from Acid Halides Section 138 Halides and Sulfonates from Alcohols Section 139 Halides and Sulfonates from Aldehydes Section 140 Halides and Sulfonates from Alkyls Section 141 Halides and Sulfonates from Amides Section 142 Halides from Amines Section 143 Halides and Sulfonates from Esters Section 144 Halides from Ethers Section 145 Halides from Halides and Sulfonates Section 146 Halides from Hydrides Section 147 Halides from Ketones Section 148 Halides and Sulfonates from Nitriles Section 149 Halides from Olefins Section 150 Halides from Miscellaneous Compounds
Section (typography)
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Shift Happens. How Halide Ion Defects Influence Photoinduced Segregation in Mixed Halide Perovskites
Minimizing photoinduced segregation in mixed halide lead perovskites is important for achieving stable photovoltaic performance. The shift in the absorption and the rate of formation of iodide- and bromide-rich regions following visible excitation of mixed halide lead perovskites is found to strongly depend on the halide ion concentration. Slower formation and recovery rates observed in halide-deficient films indicate the involvement of defect sites in influencing halide phase segregation. At higher halide concentrations (in stoichiometric excess), segregation effects become less prominent, as evidenced by faster recovery kinetics. These results suggest that light-induced compositional segregation can be minimized in mixed halide perovskite films by using excess halide ions. The findings from this study further reflect the importance of halide ion post-treatment of perovskite films to improve their solar cell performance.
Stoichiometry
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To explore the interactions between SO2 and tetraalkylammonium halide, the effects of temperature, concentration, length of alkyl chain, and halide anion on the solubility of SO2 in tetraalkylammonium halide aqueous solutions were investigated.
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Abstract Aliphatic Halides Vinylic Halides Alkynyl Halides Aromatic Halides Homologation of Halides Rearrangement of Halides
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A newly developed acyl halide molecular mechanics (MM3) force field can accurately calculate molecular geometry, usually to within experimental error. The new force field can also calculate vibrational frequencies. The acyl halides studied were formyl halides, acetyl halides, propionyl halides, n-butyryl halides, 2-methylpropionyl halides, and 2,2-dimethylpropionyl halides. The rms deviation for vibrational frequencies was 28 cm−1. © 1998 John Wiley & Sons, Inc. J Comput Chem 19: 1387–1401, 1998
Molecular mechanics
Force Field
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