Orientation Control of Functional Molecules in Langmuir-Blodgett Films Caused by a Trigger Molecule: Infrared Spectroscopic Study on the Orientation of n-Alkane, Trigger Molecule
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTOrientation Control of Functional Molecules in Langmuir-Blodgett Films Caused by a Trigger Molecule: Infrared Spectroscopic Study on the Orientation of n-Alkane, Trigger MoleculeReiko Azumi, Mutsuyoshi Matsumoto, Shin-ichi Kuroda, and Maxwell J. CrossleyCite this: Langmuir 1995, 11, 11, 4495–4498Publication Date (Print):November 1, 1995Publication History Published online1 May 2002Published inissue 1 November 1995https://pubs.acs.org/doi/10.1021/la00011a052https://doi.org/10.1021/la00011a052research-articleACS PublicationsRequest reuse permissionsArticle Views95Altmetric-Citations27LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-AlertsKeywords:
Alkane
Two-dimensional infrared spectroscopy
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Two-dimensional infrared spectroscopy
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Mid-infrared spectroscopy has been applied to zeolite structural problems. The infrared spectrum in the region of 200 to 1300 cm-1 is a sensitive tool indicating structural features of zeolite frameworks. Preliminary interpretation suggests infrared specificity for zeolite structure type and group, and for structural subunits such as double rings and large pore openings. It is proposed that the major structural groups present in zeolites can be detected from their infrared pattern. This hypothesis is based on correlation of newly determined infrared spectra of synthetic zeolites with x-ray structure data for most of the known structural classes of zeolites. Other structural information obtained from infrared studies includes framework Si/Al composition, structural changes during thermal decomposition, and cation movement during dehydration and dehydroxylation.
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The data presented show that infrared group frequencies are only applicable for specific spectra structure identification when the infrared spectrum of the unknown material is recorded in the same manner as that used to record the infrared spectra used to build the IR group-frequency data base. IR spectra recorded of compounds in different phases such as the liquid, solution, and vapor phase are useful in helping one to determine whether a compound exists in more than one rotational molecular configuration such as rotation of a CHCl 2 group about a C-C=O single bond in compounds of form CHCl 2 -C=O.
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