ChemInform Abstract: Recent Advances in Homogeneous and Heterogeneous Asymmetric Catalysis with Nitrogen‐Containing Ligands
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Homogeneous Catalysis
Homogeneous Catalysis
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Introduction.- Homogeneous redox catalysis with transition metal compounds.- Biochemical processes and metal complexes as catalysts.- Catalytic processes and human diseases.- Catalytic processes in ecological chemistry.- Homogeneous catalysis with metal complexes in chemical industry and foodstuffs chemistry.
Homogeneous Catalysis
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Homogeneous Catalysis
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Abstract The cover picture shows the concept of operating a homogeneous catalyst under continuous operation conditions: The recycling of molecular‐weight‐enlarged transition‐metal complexes by suitable filtration methods and equipment in order to combine the advantages of both classical homogeneous and heterogeneous catalysis. Various aspects of molecular‐weight enlargement and immobilization of catalysts, and recent developments, are reported in the Microreview by D. Vogt et al. on p. 4011 ff.
Homogeneous Catalysis
Filtration (mathematics)
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Homogeneous Catalysis
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Homogeneous Catalysis
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Homogeneous catalysts have many attractive properties, such as high selectivities. However, many homogeneous catalytic systems cannot be commercialized because of difficulties associated with separating the products from the catalyst. Recent approaches to tackling this problem are reviewed and compared.
Homogeneous Catalysis
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Homogeneous Catalysis
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Homogeneous Catalysis
Aqueous two-phase system
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This chapter contains sections titled: Key Reactions in Homogeneous Catalysis Coordination and Exchange of Ligands Complex Formation Acid–Base Reactions Redox Reactions: Oxidative Addition and Reductive Elimination Insertion and Elimination Reactions Reactions at Coordinated Ligands Catalyst Concepts in Homogeneous Catalysis The 16/18-Electron Rule Catalytic Cycles Hard and Soft Catalysis Hard Catalysis with Transition Metal Compounds Soft Catalysis with Transition Metal Compounds Characterization of Homogeneous Catalysts
Homogeneous Catalysis
Oxidative addition
Electron exchange
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