The enthalpy of solution of tris(dimethylamino)phosphine oxide in water
0
Citation
8
Reference
10
Related Paper
Keywords:
Phosphine oxide
Solid-state physics
Cite
Citations (3)
It is shown by approximate but reliable DFT calculations that the title compounds represent very strong superbases in gas phase and MeCN. In particular, tris-(hexamethyltriaminophosphazenyl)phosphine has a proton affinity, PA, of 295.5 kcal mol−1 and records a pKa(MeCN) of 50 ± 1 units.
Proton affinity
Cite
Citations (60)
Sodium borohydride
Cite
Citations (16)
Cite
Citations (7)
(2020). Diiron propane-1,2-dithiolate complexes with monosubstituted tris(3-chlorophenyl)phosphine or tris(4-trifluoromethylphenyl)phosphine: synthesis, characterization, crystal structures, and electrochemistry. Inorganic and Nano-Metal Chemistry: Vol. 50, No. 11, pp. 1137-1143.
Propane
Cite
Citations (2)
Cite
Citations (2)
Phosphine oxide
Cite
Citations (33)
Ligand cone angle
Cite
Citations (1)
Single crystals of the low-melting title compound, tris(n-propyl)phosphine, C9H21P, (1), and its isomer, tris(isopropyl)phosphine, (2), were grown in situ in capillaries. The crystal and molecular structures of both compounds were determined at 102 K. Compound (1) has an approximate mirror plane and C—P—C angles between 99.8 (1) and 102.3 (1)°, whereas compound (2) displays no molecular symmetry and C—P—C angles ranging from 102.0 (1) to 104.7 (1)°.
Isopropyl
Cite
Citations (8)