The thermodynamic properties of rhenium on ITS-90

Attempts to prepare rhenium hexachloride by the method described by Colton (2) have been unsuccessful. The products of the reaction were always impure rhenium oxotetrachloride and rhenium pentachloride. A compound of rhenium(VI), ReOCl 4 OPCl 3 , is shown to have a structure analogous to that of rhenium(V) ions [ReOX 4 .L] − in which the ligands are in a pseudooctahedral arrangement with L trans to the oxo-group (3). Reactions of ReOCl 4 and ReOCl 4 -OPCl 3 with pyridine and 2,2′-dipyridyl are described, and a scheme is proposed for the reactions of the products. Two stable complexes of perrhenyl chloride with the above amines have been obtained.

Perrhenate

10.1139/v71-097

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Citations (22)

The lattice constants of CuInSe2

Journal of Electronic Materials (1985)

M. L. Fearheiley K. J. Bachmann Y. H. Shing Sahira Vásquez C. R. Herrington

Stoichiometry

Lattice constant

Solid-state physics

Lattice (music)

10.1007/bf02654305

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Citations (24)

The lattice constants and magnetic anisotropy constants of electrodeposited single crystal films of hexagonal close-packed nickel

Philosophical magazine (1965)

John Wright J. Goddard

Conclusive evidence has been obtained to show that nickel may be electro-deposited to form a single crystal hexagonal structure, provided that correct bath conditions and suitable substrates are used. The measured lattice spacings of hexagonal close-packed nickel, a = (2·50 ± 0·01) Å, c = (3·98 ± 0·06) Å, agree well with the values expected. Tentative measurements of the magnetic anisotropy constants K 1 and K 2 have also been made and for films 500 Å thick have been shown to be respectively.

Lattice constant

Hexagonal Lattice

Lattice (music)

10.1080/14786436508224236

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Citations (50)

Rhenium

Per Enghag

This chapter contains sections titled: Re Facts about Rhenium Discovery Where Should Elements 43 and 75 Be Looked For? The River Rhein but not the Region Masurien A Worldwide Search for Rhenium High Concentrations of Rhenium are Unexpectedly Found at Home! Rhenium Sources in Modern Times Modern Techniques for Manufacturing Rhenium Uses of Rhenium The Biological Role of Rhenium

10.1002/9783527612338.ch29

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Syntheses and structures of trans-[ReX(CO)(Ph2PCH2PPh2)2] (X  Cl, OReO3), including a rhenium(I)-rhenium(VII) complex

Journal of Organometallic Chemistry (1993)

Ljubica Manojlović‐Muir Kenneth W. Muir M.A. Rennie Jianliang Xiao Richard J. Puddephatt

10.1016/0022-328x(93)83363-z

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Half-sandwich rhenium(III) acyl complexes: synthesis, structure and conversion to rhenium(I) and rhenium(III) isonitrile complexes

Journal of Organometallic Chemistry (1996)

Alexander C. Filippou Bernhard Lungwitz Gabriele Kociok‐Köhn Isolde Hinz

10.1016/s0022-328x(96)06401-7

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Citations (12)

Design and Synthesis of Tunable Ligands with 4,4′-Bipyridyl as an Electron-Accepting Unit and Their Rhenium Complexes

Organometallics (2017)

Takuto Kamatsuka Hiroshi Shinokubo Yoshihiro Miyake

We have designed and prepared a series of rhenium complexes with 4,4′-bipyridyl as an electron-accepting unit. Electrochemical studies revealed that oxidation and reduction of these complexes occurred on the rhenium center and the 4,4′-bipyridyl skeleton, respectively. The redox potentials of the rhenium complexes are controllable by tuning the substituents on the 4,4′-bipyridyl skeleton and the coordinating groups to the rhenium center. We have also examined the reactivity of the rhenium complexes in electrochemical and photochemical CO2 reduction.

Reactivity

Center (category theory)

10.1021/acs.organomet.7b00611

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Citations (12)