Infrared spectroscopy of organometallic ions in the gas phase: From model to real world complexes
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Abstract:
Gas phase mid-infrared spectroscopy of molecular ions can nowadays be performed with high performance mass spectrometers coupled to free electron lasers (FEL). The wide and continuous tunability of highly intense FELs in the mid-infrared region can be exploited for performing infrared multiple photon dissociation (IRMPD) spectroscopy of molecular ions. This review will focus on gas phase IRMPD spectroscopic investigations aiming at probing the structure and the reactivity of transition metal complexes. The performance of infrared spectroscopy for characterizing the coordination mode of polydentate ligands and the spin state of the metal will be illustrated. Infrared spectroscopy has also been exploited to probe the reactivity of metal complexes, and a special attention will be given to the infrared spectroscopy of reactive intermediates.Keywords:
Infrared multiphoton dissociation
Two-dimensional infrared spectroscopy
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The changes of infrared spectra and densities for Nylon 1010 under various conditions of heat treatment were studied. The polarized infrared spectra of the sample oriented by stretching were also recorded. From the factor group analysis and the normal vibrational modes comparison, a great deal of symmetry species, polarization behaviors and selective rules are obtained in terms of their symmetry properties, then the infrared bands are assigned. Some new bands which are discovered by means of separating overlapping spectral bands with computer have been discussed.
Two-dimensional infrared spectroscopy
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The use of two-dimensional infrared arrays for astronomical imaging and spectroscopy is now occurring and immensely changing the field. In view of this 'revolution' in infrared astronomy, some of the implications for future infrared spectroscopy are discussed in this paper. A method is presented for comparing the infrared background to future spectrometers at 1-5 microns. Some of the current developments in infrared spectroscopy at Mauna Kea are discussed.
Two-dimensional infrared spectroscopy
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