Meteoritic Constraints on Models of the Solar Nebula: The Abundances of Moderately Volatile Elements
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The elements are those which condense (or evaporate) in the temperature range 650 - 1350 K, as a mix of material with solar abundances is cooled (or heated) tinder equilibrium conditions. Their relative abundances in chondritic meteorites are solar (or cosmic, as defined by the composition of Cl meteorites) to within a factor of several, but vary within that range in a way that correlates remarkably well with condensation temperature, independent of chemical affinity. It has been argued that this correlation reflects a systematically selective process which favored the accretion of refractory material over volatile material from a cooling nebula. Wasson and Chou (Meteoritics 9, 69-94, 1974, and Wasson and co-authors in subsequent papers) suggested that condensation and settling of solids contemporaneously with the cooling and removal of nebular gas could produce the observed abundance patterns, but a quantitative model has been lacking. We show that the abundance patterns of the moderately volatile elements in chondritic meteorites can be produced, in some degree of quantitative detail, by models of the solar nebula that are designed to conform to observations of T Tauri stars and the global conservation laws. For example, even if the local surface density of the nebula is not decreasing, condensation and accretion of solids from radially inflowing gas in a cooling nebula can result in depletions of volatiles, relative to refractories, like those observed, The details of the calculated abundance patterns depend on (but are not especially sensitive to) model parameters, and can exhibit the variations that distinguish the meteorite classes. Thus it appears that nebula characteristics such as cooling rates, radial flow velocities, and particle accumulation rates can be quantitatively constrained by demanding that they conform to meteoritic data; and the models, in turn, can produce testable hypotheses regarding the time and location of the formation of the chondrite parent bodies and the planets.Keywords:
Volatiles
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CaAl rich refractory mineral inclusions (CAIs) found at 1 - 10% mass fraction in primitive chondrites appear to be several million years older than the dominant (chondrule) components in the same parent bodies. A prevalent concern is that it is difficult to retain CAIs for this long against gas-drag-induced radial drift into the sun. We assess a hot inner (turbulent) nebula context for CAI formation, using analytical models of nebula evolution and particle diffusion. We show that outward radial diffusion in a weakly turbulent nebula can prevent significant numbers of CAI-size particles from being lost into the sun for times of 1 - 3 x 10(exp 6) years. To match the CAI abundances quantitatively, we advocate an enhancement of the inner hot nebula in silicate-forming material, due to rapid inward migration of very primitive, silicate and carbon rich, meter-sized objects. 'Combustion' of the carbon into CO would make the CAI formation environment more reduced than solar, as certain observations imply. Abundant CO might also play a role in mass-independent chemical fractionation of oxygen isotopes as seen in CAIs and associated primitive, high-temperature condensates.
Chondrule
Refractory (planetary science)
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Abstract– Refractory materials, such as calcium‐aluminum‐rich inclusions (CAIs) and crystalline silicates, are widely found in chondritic meteorites as well as comets, taken as evidence for large‐scale mixing in the solar nebula. Most models for mixing in the solar nebula begin with a well‐formed protoplanetary disk. Here, we relax this assumption by modeling the formation and evolution of the solar nebula during and after the period when it accreted material from its parent molecular cloud. We consider how disk building impacts the long‐term evolution of the disk and the implications for grain transport and mixing within it. Our model shows that materials that formed before infall was complete could be preserved in primitive bodies, especially those that accreted in the outer disk. This potentially explains the discovery of refractory objects with low initial 26 Al/ 27 Al ratios in comets. Our model also shows that the highest fraction of refractory materials in meteorites formed around the time that infall stopped. Thus, we suggest that the calcium‐aluminum‐rich inclusions in chondrites would be dominated by the population that formed during the transition from class I to class II stage of young stellar objects. This helps us to understand the meaning of t = 0 in solar system chronology. Moreover, our model offers a possible explanation for the existence of isotopic variations observed among refractory materials—that the anomalous materials formed before the collapse of the parent molecular cloud was complete.
Refractory (planetary science)
Refractory metals
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The primitive solar nebula was a violent and chaotic environment where high energy collisions, lightning, shocks and magnetic re-connection events rapidly vaporized some fraction of nebular dust, melted larger particles while leaving the largest grains virtually undisturbed. At the same time, some tiny grains containing very easily disturbed noble gas signatures (e.g., small, pre-solar graphite or SiC particles) never experienced this violence, yet can be found directly adjacent to much larger meteoritic components (chondrules or CAIs) that did. Additional components in the matrix of the most primitive carbonaceous chondrites and in some chondritic porous interplanetary dust particles include tiny nebular condensates, aggregates of condensates and partially annealed aggregates. Grains formed in violent transient events in the solar nebula did not come to equilibrium with their surroundings. To understand the formation and textures of these materials as well as their nebular abundances we must rely on Nucleation Theory and kinetic models of grain growth, coagulation and annealing. Such models have been very uncertain in the past: we will discuss the steps we are taking to increase their reliability.
Chondrule
Presolar grains
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We have developed a simple model of global transport of solids in the protoplanetary nebula, including radial drift of large particles and diffusion of small ones. The model has been applied to the formation and redistribution of the Ca-A1 rich refractory mineral inclusions (CAIs) found in primitive chondrites. These objects form at much higher temperatures, and appear to be 1-3 million years older than, the dominant (chondrule) components found in the same parent bodies. A widespread concern has been the retention of CAIs for this long against gas-drag-induced radial drift into the sun. We show that outward radial diffusion in a weakly turbulent nebula can overwhelm inward drift, and prevent significant numbers of CAI-size particles from being lost into the sun for tines on the order of several Myr. An element of this model is rapid inward radial drift of boulder-sized primitive (carbon-rich) silicate material, more like Halley-dust than CI chondrites in the early days of the nebula. Thls process can enrich the abundance of silicate and carbon material in the inner nebula, and may provide possible explanations for both chemical and isotopic properties of CAIs. The predicted enhancement of CO relative to water might be of relevance to recent IR astronomical observations of CO in the inner disks of several actively accreting T Tauri stars. This process has applications to the transport and redistribution of volatiles in general. Depending on the rubble particle size distribution, rapid radial drift of boulder-sized solids can bring more material inwards across a condensation front, to evaporate, than can subsequently be removed by nebula advection or diffusion, until a strong local enhancement is produced which allows diffusive loss to balance the drifting source. Application of this process to enhancement of the abundance of water near the ice line will be discussed. Supported by the Origins of Solar Systems program.
Chondrule
Protoplanet
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Refractory (planetary science)
Outgassing
Chondrule
Volatiles
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Abstract— Models of the solar nebula are constructed to investigate the hypothesis that surviving planetary objects began to form as the nebula cooled from an early, hot epoch. The imprint of such an epoch might be retained in the spatial distribution of planetary material, the systematic deviations of its elemental composition from that of the Sun, chemical indicators of primordial oxidation state, and variations in oxygen and other isotopic compositions. Our method of investigation is to calculate the time‐dependent, two‐dimensional temperature distributions within model nebulas of prescribed dynamical evolution, and to deduce the consequences of the calculated thermal histories for coagulated solid material. The models are defined by parameters which characterize nebular initial states (mass and angular momentum), mass accretion histories, and coagulation rates and efficiencies. It is demonstrated that coagulation during the cooling of the nebula from a hot state is expected to produce systematic heterogeneities which affect the chemical and isotopic compositions of planetary material. The radial thermal gradient at the midplane results in delayed coagulation of the more volatile elements. Vertical thermal gradients isolate the most refractory material and concentrate evaporated heavy elements in the gas phase. It is concluded that these effects could be responsible for the distribution of terrestrial planetary masses, the systematic depletion patterns of the moderately volatile elements in chondritic meteorites and the Earth, the range of oxygen isotopic compositions exhibited by calcium‐aluminum‐rich inclusions (CAIs) and other refractory inclusions, and some geochemical evidence for a moderately enhanced oxidation state. However, nebular fractionations on a global scale are unlikely to account for the more oxidizing conditions inferred for some CAIs and chondritic silicates, which require dust enhancements greater than a few hundred. This conclusion, along with the well‐established evidence from studies of chondrules and CAIs for thermal excursions of short duration, make it likely that local environments, unrelated to nebular thermal evolution, were also important.
Refractory (planetary science)
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Isotopic abundances of short-lived radionuclides such as 26Al provide the most precise chronometers of events in the early solar system, provided that they were initially homogeneously distributed. On the other hand, the abundances of the three stable isotopes of oxygen in primitive meteorites show a mass-independent fractionation that survived homogenization in the solar nebula. As as result of this and other cosmochemical evidence, the degree of spatial heterogeneity of isotopes in the solar nebula has long been a puzzle. We show here that based on hydrodynamical models of the mixing and transport of isotopic anomalies formed at, or injected onto, the surface of the solar nebula, initially high levels of isotopic spatial heterogeneity are expected to fall to steady state levels (~10%) low enough to validate the use of 26Al for chronometry, but high enough to preserve the evidence for mass-independent fractionation of oxygen isotopes. The solution to this puzzle relies on the mixing being accomplished by the chaotic fluid motions in a marginally gravitationally unstable disk, as seems to be required for the formation of gas giant planets and by the inability of alternative physical processes to drive large-scale mixing and transport in the planet-forming midplane of the solar nebula. Such a disk is also capable of large-scale outward transport of the thermally annealed dust grains found in comets, and of driving the shock fronts that appear to be responsible for much of the thermal processing of the components of primitive meteorites, creating a self-consistent picture of the basic physical processes shaping the early solar nebula.
Presolar grains
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A compilation of data on 78 elements in the nine groups of chondrites shows each to be isochemical with the exception of a few volatiles. With the exception of the most volatile elements, the groups have solar abundances to within a factor of two. The solar abundances and the chemical and physical properties of phases in the leastaltered chondrites indicate formation by grain agglomeration in the preplanetary nebula. Planets formed by the gradual growth of bodies in the solar nebula. Because there is no evidence for the formation of non-chondritic bodies in the nebula, the simplest model calls for the bulk compositions of the terrestrial planets to be chondritic. Mercury is enriched in metal, perhaps either because of high loss of silicates due to enhanced radial drag in the innermost part of the nebula, or because of enhanced accretion of metallic cores from disrupted asteroids. Chondritic compositions should be considered as boundary conditions for planetary models.
Chondrule
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Cosmochemistry
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Abstract— The accumulation of presolar dust into increasingly larger aggregates such as calcium‐aluminum‐rich inclusions (CAIs) and chondrules, asteroids, and planets should result in a drastic reduction in the numerical spread in oxygen isotopic composition between bodies of similar size, in accord with the central limit theorem. Observed variations in oxygen isotopic composition are many orders of magnitude larger than would be predicted by a simple, random accumulation model that begins in a well‐mixed nebula, no matter what size objects are used as the beginning or end points of the calculation. This discrepancy implies either that some as yet unspecified but relatively long‐lived process acted on the solids in the solar nebula to increase the spread in oxygen isotopic composition during each and every stage of accumulation, or that the nebula was heterogeneous (at least in oxygen) and maintained this heterogeneity throughout most of its nebular history. Depending on its origin, large‐scale nebular heterogeneity could have significant consequences for many areas of cosmochemistry, including the application of well‐known isotopic systems to the dating of nebular events and the prediction of bulk compositions of planetary bodies on the basis of a uniform cosmic abundance. The evidence supports a scenario wherein the oxygen isotopic composition of nebular solids becomes progressively depleted in 16 O with time due to chemical processing within the nebula, rather than a scenario where 16 O‐rich dust and other materials are injected into the nebula, possibly causing its initial collapse.
Central limit theorem
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