Total synthesis of rifamycin W

Masaya Nakata,Nobutake Akiyama,Kyoko Kojima,Hirokazu Masuda,Mitsuhiro Kinoshita,Kuniaki Tatsuta

Total synthesis of rifamycin W

1990

Masaya Nakata
Nobutake Akiyama
Kyoko Kojima
Hirokazu Masuda
Mitsuhiro Kinoshita
Kuniaki Tatsuta

Abstract The first total synthesis of rifamycin W ( 1 ) has been accomplished by coupling two segments of the aliphatic ansa-chain 2 and the aromatic chromophore 3 , elucidating the absolute structure completely.

Keywords:

Total synthesis
Chromophore
Photochemistry
Rifamycin
Quinone
Lactam
Organic chemistry
Chemistry
Stereochemistry
absolute structure

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