Kinetics and temperature evolution during the bulk polymerization of methyl methacrylate for vacuum-assisted resin transfer molding

Abstract Curing reactions of methyl methacrylate (MMA) comprise an induction time of gradual temperature change over tens of minutes, followed by a sudden temperature rise within tens of seconds because of auto-acceleration known as the Trommsdorff effect. These curing effects were investigated as initial initiator and polymer concentrations were varied. A mathematical model combining the reaction kinetics with heat transfer was developed and verified in its ability to simulate the processing kinetics and temperature evolutions throughout thick MMA-based parts. It was further demonstrated that the processing conditions at specific points within a part during manufacture could be actively controlled via the Trommsdorff effect by locally varying the initial concentration of poly(methyl methacrylate) (PMMA) solution. Together, these advancements provide an enhanced ability to design and optimize the manufacture of thick, large-scale PMMA materials by taking advantage of auto-acceleration instead of avoiding it.