Impact of Solution Chemistry and Particle Anisotropy on the Collective Dynamics of Oriented Aggregation

Although oriented aggregation of particles is a widely recognized mechanism of crystal growth, the impact of many fundamental parameters, such as crystallographically distinct interfacial structures, solution composition, and nanoparticle morphology, on the governing mechanisms and assembly kinetics are largely unexplored. Thus, the collective dynamics of systems exhibiting OA has not been predicted. In this context, we investigated the structure and dynamics of boehmite aggregation as a function of solution pH and ionic strength. Cryogenic transmission electron microscopy shows that boehmite nanoplatelets assemble by oriented attachment on (010) planes. The coagulation rate constants obtained from dynamic light scattering during the early stages of aggregation span 7 orders of magnitude and cross both the reaction-limited and diffusion-limited regimes. Combining a simple scaling analysis with calculations for stability ratios and rotational/translational diffusivities of irregular particle shapes, the ef...