A hybrid aluminum/hydrogen/air cell system

Abstract A hybrid aluminum/hydrogen/air cell system is developed to solve the parasitic hydrogen-generating problem in an alkaline aluminum/air battery. A H 2 /air fuel cell is integrated into an Al/air battery so that the hydrogen generated by the parasitic reaction is utilized rather than wasted. A systematic study is conducted to investigate how the parasitic reaction and the added H 2 /air cell affect the performance of the aluminum/air battery. The aluminum/air sub-cell has an open circuit voltage of 1.45 V and the hydrogen/air sub-cell of 1.05 V. The maximum power density of the entire hybrid system increases significantly by ∼20% after incorporating a H 2 /air sub-cell. The system maximum power density ranges from 23 to 45 mW cm −2 in 1–5 M NaOH electrolyte. The hybrid system is adaptable in concentrated alkaline electrolyte with significantly improved power output at no sacrifice of its overall efficiency.