Rearrangement of 3-membered 1,1,2-trifluorobromonium and iodonium ions and comparison of trifluorochloronium to fluorocarbenium ions.
2008
Abstract : In this paper we investigate the influence that a 4-halosubstituent has on formation of three-membered halonium ions and their rearrangement to five-membered ring intermediates when chloronium, bromonium and iodonium ions from alkenes 1, 2 and 3 are formed in aprotic solvent (Scheme 1). We also compare the open-ion chloronium ions with the open-carbocations from addition of a proton to terminal fluorosubstituted alkenes.
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