Band Spacing in Poly(3-hydroxybutyrate) and Its Blends with Poly(propylene carbonate): Dependence on Thermal Processing

The band spherulites grown in neat poly(3-hydroxybutyrate) (PHB) and its blends with poly(propylene carbonate) (PPC) were observed by polarized optical microscopy. For the spherulites in neat PHB, it is evident that the band spacing increases first and then decreases with melting time. As the melting time is within 7 min, the band spacing increases continuously, which should be attributed to increasing mobility of polymer chains or decreasing viscosity of the melt. When the melting time is prolonged, evident thermal degradation of PHB occurs and results in a great deal of noncrystalline fractions, which is similar with addition of miscible amorphous polymers in the melt, and the band spacing decreases accordingly. The thermal degradation of PHB cannot, however, be detected by a thermogravimetric analyzer because of less volatile productions. An evident decrease of molecular weight can be measured by gel permeation chromatography, indicating occurrence of serious degradation. The decrease of crystallizatio...