The kinetic product of the octabromination of p-tert-butylcalix[8]arene octamethyl ether
2014
Abstract A new isomer, not previously detected, is the kinetic product of the octabromination (NBS, CH2Cl2, rt, 60 W Vis irradiation) of p-tert-butylcalix[8]arene octamethyl ether. On the basis of the signal pattern in the NMR spectrum, and the splitting of methoxy signals in the presence of a chiral solvating agent, the isolated product is assigned as one of the two possible achiral forms of Cs symmetry, where the mirror symmetry operation bisects two opposite aryl rings.
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
1
References
0
Citations
NaN
KQI