Assoziation in Lösung. Eine graphische Methode zur Bestimmung von Gleichgewichtskonstanten aus kolligativen Eigenschaften

A graphical procedure for the evaluation of association equilibria in solution is given. It consists of families of master plots that are superimposed on a diagram of experimental values (namely practical osmotic coefficient vs. concentration). Different models (dimerisation, multimerisation, chain association) can be tested, and the values of up to two association constants can be read off. Tables of the normalized variables and various examples are presented.