Unexpected Magnetic Behavior of Dinuclear Co(II) Complex in Dithiocarbamates: A Possibility of Intramolecular Exchange Interactions

This study mainly interested in the magnetism of tetrahedrally coordinated dinuclear cobalt (II) complexes. Using the observed room temperature magnetic measurements suggested that the predicted magnetic behavior has to be tested with additional experimental measurements in order to testify the validity of the UV measurements. Using the theoretical background for magnetic behavior of Co(II) ion in a tetrahedral coordination, it is strongly recommended that the proposed structure of the complex has to be tested with additional characterization.