Synthesis of (+)-goniopypyrone and (+)-goniotriol using Pd-catalyzed carbonylation
2019
Abstract Syntheses of (+)-goniopypyrone and (+)-goniotriol isolated from Goniothalamus giganteus were achieved. The key steps involve Pd-catalyzed carbonylation for lactone ring formation and diastereoselective reduction of ynone using the (R)-CBS catalyst and borane dimethyl sulfide complex.
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