Self-assembly of polyhedral metal–organic framework particles into three-dimensional ordered superstructures
2018
Colloidal particles of metal–organic frameworks (ZIF-8 and UiO-66) with different polyhedral shapes can self-assemble into well-ordered, porous three-dimensional superstructures. These superstructures function as photonic crystals, with a photonic band gap that depends on the size of the MOF particles and shifts upon the sorption of guests within their pores.
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