An Alternative Synthesis of2-Alkylidene-3,4-dihydro-2H-1,4-benzoxazines byIntramolecular Gold-Catalyzed Hydroalkoxylation of 2-(Prop-2-yn-1-ylamino)phenols
2011
An efficient gold-catalyzed procedure to synthesize 2-alkylidene-3,4-dihydro-2H-1,4-benzoxazines has been developed starting from 2-alkynyl-substituted phenols. This is an intramolecular hydroalkoxylation reaction on alkynes tethered to a phenol moiety that represents a valuable alternative to the already reported transition-metal-catalyzed procedures.
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