Characteristics of rare-earth elements (REE), strontium and neodymium isotopes in hydrothermal fluorites from the Bailashui tin deposit in the Furong ore field, southern Hunan Province, China

In this paper the authors present the REE concentrations and Sr and Nd isotopic compositions of fluorites from the Bailashui tin deposit of the Furong ore field, southern Hunan Province. The results showed that the total amount of REE in fluorites is usually low, ranging from 0.705 to 8.785 μg/g with the chondrite-normalized REE distribution patterns similar to those of the Qitianling granites in the study area, characterized by LREE-enrichment patterns with pronounced negative Eu anomalies. The fluorites vary in Sr isotopic composition within the range of 0.7083–0.7091, the values are lower than those of the granites and higher than those of the host carbonate rocks in this area. The ɛNd(t) values of fluorites vary between −9.4 and +10.3, revealing that both the crust-and mantle-source materials were involved in the ore-forming hydrothermal fluids. Combined with previous studies on this ore deposit, the Bailashui tin deposit is temporally and spatially closely related with granitic magmatism in this area. The hydrothermal fluorites are the product of fluid/rock interactions between granitic magmatic hydrothermal fluid and marine carbonate rocks. The REE and F in the ore-forming fluid were derived from the granites, whereas Sr in the ore-forming fluid came mainly from the granitic magmatic hydrothermal fluid and marine carbonate rocks, although variations in Sr isotopic composition cannot be explained by a simple mixture of these two end-members. Evidence demonstrated that the ore-forming fluids are of crustal-mantle mixing origin, but that the fluids were probably incompletely homogenized and this may be caused by inhomogeneous mixing of the fluids of different sources.