NEW LOW-VALENT TITANIUM CATALYZED REACTION OF CHLORODIFLUOROMETHYL KETONES LEADING TO α,α-DIFLUORINATED β-HYDROXY KETONES
1985
Various chlorodifluoromethyl ketones underwent the aldol-type reaction with aldehydes or ketones by the action of titanium tetrachloride and zinc reagent in tetrahydrofuran at room temperature to give moderate to good yields of α,α-difluorinated β-hydroxy ketones.
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