Porous Li-MOF as a solid-state electrolyte: exploration of lithium ion conductivity through bio-inspired ionic channels.

A rarely porous Li-MOF (Li-AOIA) with surface area of 605 m2 g-1 was employed for the formation of an emerging class of solid-state lithium ion electrolytes. Infiltration of LiBF4 into Li-AOIA afforded Li-AOIA@BF4 with ionic conductivity of 1.09 × 10-5 S cm-1 at room temperature and an activation energy of 0.18 eV.