Fullerene derivatives, and macrocyclic polyamines single preparation

The present invention discloses a single fullerene macrocyclic polyamine derivatives and a preparation method, which is characterized by a single fullerene derivative macrocyclic polyamine intermediate compound (10) 90mg (71.3μmol) ~ 180mg (142.6 [mu] mol) was dissolved in CH2Cl2 50 ~ 80mL, under stirring slowly added dropwise CF3COOH 1.0mL (13.4mmol) ~ 2.0mL (26.8mmol), at room temperature for 18 ~ 24h, and the reaction until complete disappearance of starting material was monitored by TLC. The reaction mixture solvent was removed under reduced pressure, and other low-boiling impurities, to obtain a brown solid polyamine derivative of fullerene single macrocycle 80 ~ 157.3mg, yield 85.2% ~ 90.1%; fullerene single macrocyclic polyamine derivative is of the formula: