N-2-Selective gold-catalyzed alkylation of 1-sulfonyl-1,2,3-trizoles
2017
An efficient new method was developed to synthesise N-2-alkyl-1,2,3-trizoles via gold catalyzed alkylation of 1-sulfonyl-1,2,3-trizoles with vinyl ethers. Only N-2-isomers were obtained in these reactions. The sulfonyl group in the 1-sulfonyl-1,2,3-trizoles acted as the leaving group, which was trapped by H2O in this reaction.
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