Luminescence self-quenching in Tm3+: YLF crystals: II. The luminescence decay and macrorates of energy transfer

Microparameters of migration and self-quenching of luminescence from the (3 P 0, 1 I 6) levels of Tm 3+ ions are calculated and the luminescence decay from the 3 H 4, 1 G 4, and 1 D 2 levels are analyzed in the concentration series of LiY1−x TmxF4(x=0.5–10 at. %) crystals upon weak selective excitation. It is shown that the luminescence decay of a thulium ion concentration higher than 0.5 at. % cannot be described by the energy transfer that takes into account only the dipole-dipole interaction. The comparison of experimental kinetic curves with theoretical curves calculated within the framework of the known energy transfer models showed that multipole-multipole interaction is responsible for the self-quenching of the thulium levels. Contributions of higher multipole interactions to the self-quenching are estimated. The decay of luminescence from the 3 H 4, 1 G 4, and 1 D 2 levels of Tm3+:YLF crystals with different concentrations of thulium ions is described analytically.