Novel three-dimensional electrode device for treating wastewater difficult in biologically degrading

The invention discloses a novel three-dimensional electrode device for treating wastewater difficult in biologically degrading. The novel three-dimensional electrode device comprises electrochemical catalysis oxidization cathode electrode plates and electrochemical catalysis oxidization anode electrode plates, which are alternated in a reactor, and also comprises a micropore aeration plate arranged at the bottom of the reactor and an iron-carbon micro-electrolysis filler of a three-dimensional electrode, wherein wastewater enters the device and then sequentially enters through holes of all stages of electrode plates and then flows out, and aeration of small bubbles is carried out through micropores in the micropore aeration plate at the bottom of the reactor. According to the novel three-dimensional electrode device, main harmful pollution sources in pesticide wastewater, printing and dyeing wastewater and pharmaceutical wastewater can be efficiently degraded and removed through catalytic oxidization, and the wastewater difficult in biologically degrading is completely degraded or harmless or degradable wastewater with low-grade organic matters is generated. The novel three-dimensional electrode device has the advantages of high operation efficiency, easiness in installation and small occupation area, can ensure that COD (Chemical Oxygen Demand), TOC (Total Organic Carbon) and chroma removing rate of the wastewater difficult in biologically degrading is high due to the adoption of singe-class effluent, can be used for completely degrading toxic pollutants in the wastewater, and is stable in effluent quality.