Soil formation in Greyzems in Moscow district: micromorphology, chemistry, clay mineralogy and particle size distribution

Abstract Greyzems (Grey Forest Soils) are zonal soils of the forest–steppe, in Russia geographically situated between the (Podzo) Luvisols of the southern taiga forest and the (Luvic) Chernozems of the steppe. Greyzems are characterized by a dark mollic horizon, with uncoated (bleached) silt and sand grains on pedfaces, and an argic horizon as diagnostic horizons. The FAO–Unesco soil map of the world shows Greyzems and Luvisols in Russia at this transition (the Russian soil map shows only Greyzems), while in similar geographic position in the USA and Canada the proportion of Greyzems is very small and Luvic Phaeozems/Chernozems and Albic Luvisols occupy those transitional zones of the grassland–forest interface. Three Greyzem profiles, presently under forest, and developed on loess-like mantle loams of Late Weichselian (Valday) age in the northern forest–steppe zone of the East European plain (Middle Russian Upland) were described and sampled near Pushchino, some 100 km south of Moscow. Micromorphology, particle size data, chemical data and clay mineralogy were studied. Based on the particle size distribution and the occurrence of fragments of a second humus horizon (SHH) the presence of two, rather similar, deposits in the solum is advocated. The following processes have been deduced from the study: (i) decalcification and secondary accumulation of carbonates; (ii) humus accumulation, including the significance of the SHH; (iii) clay illuviation, presumably two main phases; (iv) biological activity; (v) degradation of the mollic A: occurrence of bleached grains; (vi) downward migration of textural components and organic matter, in the Bt horizon along major pedfaces: occurrence of black organo-clay coatings and uncoated silt/sand grains; (vii) gleying. The tentative sequence of these processes during Late Weichselian and Holocene times leads us to conclude that Greyzems are polygenetic. They formed as Podzo(Luvisols) under forest, with fine clay coatings in the fine pores inside the blocky and prismatic peds, in the Late Glacial and Early Holocene. The change to tall grass steppe in the Atlanticum created a mollic horizon, that degrades when forest re-invades during the Subatlanticum. Fine clay, combined with organic matter forms black coatings on the major pedfaces. Uncoated silt and sand particles also migrate downward along those major pedfaces. Biological activity is involved in the very complex pattern of the transitional AhE and EBt horizons. Active gleying only occurs in the profile on the lowest topographic position. These latter processes are still active today. Similar soils do occur in the grassland–forest interface in North America, except where the younger age of the landscape and high CaCO3 content at shallow depth prevented their full development.