Nonenzymatic, Enantioconvergent Dynamic Kinetic Resolution (DKR) of Racemic 2-(1H-Pyrrol-1-yl)alkanoic Acids as α-Amino Acid Equivalents

Eri Tokumaru,Atsushi Tengeiji,Takayoshi Nakahara,Isamu Shiina

Nonenzymatic, Enantioconvergent Dynamic Kinetic Resolution (DKR) of Racemic 2-(1H-Pyrrol-1-yl)alkanoic Acids as α-Amino Acid Equivalents

2015

Eri Tokumaru
Atsushi Tengeiji
Takayoshi Nakahara
Isamu Shiina

We report an effective dynamic kinetic resolution (DKR) system of racemic 2-(1H-pyrrol-1-yl)alkanoic acids, which consists of a rapid racemization step via an activating substrate and an enantio-di...

Keywords:

Organic chemistry
Amino acid
Chemistry
Kinetic resolution
Equivalent
Biochemistry
Racemization
Substrate (chemistry)

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