Nickel-Catalyzed Multicomponent Coupling of Alkyne, Buta-1,3-diene, and Dimethylzinc under Carbon Dioxide

Yasuyuki Mori,Takamichi Mori,Gen Onodera,Masanari Kimura

Nickel-Catalyzed Multicomponent Coupling of Alkyne, Buta-1,3-diene, and Dimethylzinc under Carbon Dioxide

2014

Yasuyuki Mori
Takamichi Mori
Gen Onodera
Masanari Kimura

A nickel catalyst promoted the coupling of alkynes with buta-1,3-diene and dimethylzinc under carbon dioxide to provide (5 E ,8 Z )-2-vinyldeca-5,8-dienoic acids with high regio- and stereoselectivity.

Keywords:

Photochemistry
Diene
Carbon dioxide
Alkyne
Carboxylation
Catalysis
Organic chemistry
Dimethylzinc
Nickel
Chemistry
Inorganic chemistry
Substituent

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