Heat conductive composite material with high volume fraction and preparation method thereof

The invention discloses a heat conductive composite material with a high volume fraction. The composite material is characterized by being composed of a heat conductive filling material, which is irregularly stacked to form a heat conductive network and accounts for 90 to 99% of the total weight of the composite material, and a polymer adhesive, which is dispersed in the cavities in the heat conductive network and accounts for 1 to 10% of the total weight of the composite material, wherein the heat conductive filling material is high heat conductive carbon-base micro nano powder. The moulded products can be prepared through the steps of direct mixing and hot press molding, and the preparation efficiency is high. The preparation of the composite material is simple and convenient. Moreover the content of the high heat conductive carbon-base micro nano powder filling material is high, so the composite material can meet the realistic requirements on massive production. The prepared heat conductive composite material has an excellent heat conductive performance and mechanical properties, also has a certain electric conductive performance, and can be used in fields like 3D printing materials, notebook, large power LED luminescence, panel display, digital camera, and mobile communication products and related compact and high-speed electronic elements.