Solvothermal route synthesis of single-crystalline α-MnO2 nanowires

Abstract Single-crystalline α-MnO 2 nanowires with diameters of 10–30 nm and lengths to several micrometers have been successfully synthesized by hydrothermally treating a mixed solution of Mn 2 O 3 and KOH at 180 °C for 24 h. The morphology and the crystal structure of the final products were characterized. The cyclic voltammetry curve of the products indicated that the α-MnO 2 nanowires are promising electrode material for applications in super capacitors. The specific capacity of the electrode deduced from the cyclic voltammograms curve is 185 F g −1 . The magnetic properties of the products have been evaluated using a vibrating magnetometer and results show that the α-MnO 2 nanowires exhibit ferromagnetic characteristics at room temperature.