Stereochimie de la reaction magnesienne sur deux amines bromees ethyleniques: N-benzyl N-ethyl amino-3 methyl-2 bromo-1 propene-1 et le N-benzyl N-ethyl amino-3 bromo-1 propene-1
1976
Abstract The synthesis of vinylorganomagnesium compounds with N -benzyl- N -ethyl-3-amino-2-methyl-1-bromo-1-propene or with trans-N -benzyl- N -ethyl-1-bromol-1-propene is not stereospecific. The same reaction realised with the cis isomer gives two compounds: cis product and acetylene derivate.
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