Study of Ceria Sulfation

Abstract The oxidative adsorption of SO 2 on ceria has been studied using gravimetry and IR spectroscopy. SO 2 oxidation gives rise to two main types of sulfates: surface and bulklike species. The former are characterized by IR bands in the 1400-1340 cm −1 range while the latter lead to a very broad band near 1200 cm −1 . Their relative amount depends on the sample surface area and the total sulfate amount formed. The sulfate thermal stability and reducibility are compared to those of sulfate species formed on other oxides. It is also found that oxidation of SO 2 adsorbed species into sulfate can occur without O 2 addition, a concomitant ceria reduction then being evidenced by UV-visible reflectance spectroscopy.