Ultrafast Dynamic Microscopy of Carrier and Exciton Transport

We highlight the recent progress in ultrafast dynamic microscopy that combines ultrafast optical spectroscopy with microscopy approaches, focusing on the application transient absorption microscopy (TAM) to directly image energy and charge transport in solar energy harvesting and conversion systems. We discuss the principles, instrumentation, and resolutions of TAM. The simultaneous spatial, temporal, and excited-state-specific resolutions of TAM unraveled exciton and charge transport mechanisms that were previously obscured in conventional ultrafast spectroscopy measurements for systems such as organic solar cells, hybrid perovskite thin films, and molecular aggregates.We also discuss future directions to improve resolutions and to develop other ultrafast imaging contrasts beyond transient absorption. Expected final online publication date for the Annual Review of Physical Chemistry Volume 70 is April 20, 2019. Please see http://www.annualreviews.org/page/journal/pubdates for revised estimates.