Widespread late Neoarchean reworking of Meso- to Paleoarchean continental crust in the Anshan-Benxi area, North China Craton, as documented by U-Pb-Nd-Hf-O isotopes

We present an integrated study of zircon U-Pb dating and O-Hf isotopic analyses combined with whole-rock geochemistry and Nd isotopic systematics on widespread late Neoarchean syenogranites (Qidashan Pluton) and other granitoids (granodiorite, quartz monzonite, monzogranite) in the Anshan-Benxi area, eastern North China Craton. All these rocks were emplaced at ca. 2.5 Ga according to SHRIMP zircon U-Pb dating and other indirect methods. The syenogranites are characterized by high SiO2 and K2O/Na2O and low CaO, FeOt, MgO, TiO2 and P2O5. However, they differ in trace element and REE compositions and can be roughly subdivided into two types. Type 1 syenogranite has strongly negative Eu anomalies and Ba depletion, with large variations of LREE to HREE differentiation; type 2 syenogranite has no negative Eu anomaly and Ba depletion. Other granitoids are also rich in K2O and show similar trace element and REE compositional features as the type 2 syenogranite. Most syenogranite samples have whole-rock eNd(t) values of –10.5 to –2.7 and tDM(Nd) ages of 2.96 to 3.90 Ga, whereas the other granitoids have eNd(t) values of –5.2 to –2.2 and tDM(Nd) ages of 2.95 to 3.19 Ga. Magmatic zircon from the syenogranites has eHf(t) values and Hf crustal model ages ranging mainly from –11.0 to +4.4 and 2.70 to 3.46 Ga, respectively; those from other granitoids have eHf(t) values and Hf crustal model ages of –16.0 to +2.4 and 2.81 to 3.72 Ga, respectively. All these rocks contain Meso- to Paleoarchean xenocrystic zircon grains with eHf(t) values and Hf crustal model ages ranging from –14.3 to +8.3 and 2.79 to 3.93 Ga, respectively. Decoupling of whole-rock Nd and Hf-in-zircon isotopes occurs in some samples. Most low-U magmatic zircon (U