Total Synthesis of the Anti-Apoptotic Agents Iso- and Bongkrekic Acids
2010
The first convergent total synthesis of isobongkrekic acid is reported involving three different stereospecific palladium cross-couplings for the formation of the diene units. Access to bongkrekic acid by this route is also demonstrated. These syntheses involve the formation of several potentially general building blocks.
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