Rational anode design for protonic ceramic fuel cells by a one-step phase inversion method

Abstract A one-step phase inversion method was applied to fabricate an optimized anode structure for protonic ceramic fuel cells (PCFCs). The phase inversion process utilized raw starting chemicals, instead of crystalline BaCe 0.7 Z r0.1 Y 0.1 Yb 0.1 O 3-δ (BCZYYb) powder in an energy and time saving process. The resulting large and fingerlike pores exhibited enhanced performance as compared to the disordered pores produced by conventional preparation of anode structures using dry pressing methods. The electrochemical performance of the rational designed anode supported cell were 491, 402, 302 and 200 mW cm −2 at 700, 650, 600 and 550 C, respectively, which was nearly twice than the cell with dry pressing anode. An equivalent circuit modeling method was used to separate the anode polarization resistance from the single cell, confirming that the overall cell performance improvements were attributed to microstructural modifications of the anode by the phase inversion process. The one-step phase inversion method demonstrated great promise for improved processing of fuel cells and separation membranes.