Catalytic application of recyclable silica-supported bismuth(III) chloride in the benzo[N,N]-heterocyclic condensation
2013
Abstract Silica-supported bismuth(III) chloride (BiCl 3 /SiO 2 ) has been successfully employed in the condensation of 1,2-dicarbonyls with a variety of arene-1,2-diamines bearing either electron withdrawing or donating functional groups. The catalyzed reaction proceeded smoothly under ambient temperature in methanol to give the corresponding quinoxaline and pyrido[2,3- b ]pyrazine compounds in good to excellent yields. The catalyst exhibited remarkable reusable activity and higher catalytic performance than homogeneous BiCl 3 . A plausible mechanism for the catalytic action of BiCl 3 /SiO 2 has been introduced. Moreover, the crystal structure of the prepared unsymmetrical benzo[ N , N ]-heterocycles has been determined by single crystal X-ray diffraction.
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